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MOV are bidirectional components suitable for both AC and DC circuits, TVS are most often unidirectional, despite bidirectional TVS are also available; conducts more current compared to TVS diod...
Answer
#1: Initial revision
* MOV are bidirectional components suitable for both AC and DC circuits, TVS are most often unidirectional, despite bidirectional TVS are also available; * conducts more current compared to TVS diodes (in general); * dissipates energy in a solid material and not in a junction. I would use a MOV where I need to dissipate a lot of power. But that's just a declaration of principle. The detailed answer of Olin is the right way.